Tag Archives: polybrominated diphenyl ethers

Toxic flame retardants gain attention of U.S. consumer commission

Ongoing studies into flame retardant chemicals have raised a serious question: Are ANY of the polybrominated or polychlorinated flame retardants safe enough to be used in household products?

It’s a question I’ve been asking for several years while writing about these chemicals, many of which are known to disrupt hormonal functions in humans and animals. Among them are the familiar polybrominated diphenyl ethers, or PBDEs.

Now the U.S. Consumer Product Safety Commission is weighing in on the question by proposing new regulations that would ban this entire class of chemicals containing bromine or chlorine — now referred to as nonpolymeric organohalogen flame retardants. If these regulations are eventually adopted, they would prohibit the use of organohalogens in four types of products:

  • Any children’s product, including toys and baby furniture, except for car seats,
  • Any type of seat cushion or upholstered furniture,
  • Any mattress or mattress pad, and
  • Any plastic case containing an electronic device, including computers and televisions.

Banning an entire class of chemicals is a fairly radical step, because each chemical in this large group of compounds has its own toxicity profile. Even the staff of the Consumer Product Safety Commission recommended against such a broad regulation. If you are up for some dense reading on the subject, check out the 535-page briefing report (PDF 78.7 mb) or just read the summary in National Law Review.

Despite the opposition by CPSC staff, three out of five commissioners were convinced of the dangers imposed by this broad class of chemicals. They voted, 3-2, to move ahead with a total ban. Convincing documents included a petition for rulemaking (PDF 63 mb) from 12 diverse groups, ranging from the American Academy of Pediatrics to the International Association of Fire Fighters to Consumers Union. The commission also heard formal testimony from these groups and many others. (Review the videos on this page.)

“It is imperative that CPSC’s regulation cover all organohalogen flame retardants as a class when used in consumer products,” states the petition. “This class of chemicals is foreign to the mammalian body and inherently toxic, due to its physical, chemical and biological properties.

“Industry has historically responded to the dangers posed by one organohalogen flame retardant by replacing it with one or more other organohalogens that are, by virtue of their chemical properties, also harmful,” the petition continues. “This exposes consumers to a series of ‘regrettable substitutions’ from one harmful flame retardant to another… The way to end this cycle of toxicity is to ban all products in the categories at issue here if they contain any organohalogen flame retardant.”

A total ban was ultimately the position taken by the commission, although formal rulemaking will take time and may not come to pass. At least two commissioners asked on several occasions if even one of these flame retardants has been proven safe. They never received an answer that satisfied them.

After the vote, Commissioner Elliott Kaye, an attorney, issued a strongly worded written statement (PDF 262 kb): to explain why he agreed to take such a strong action.

“As a policymaker and, more importantly, as a parent, I am horrified and outraged at how chemicals are addressed in this country,” he said. “It is completely irrational that we wait for children to be poisoned before the government is allowed to step in.

“Rational and thoughtful public policy in this area would involve the government and industry coming together to agree which chemicals are safe for human exposure, especially for pregnant women and children, and which ones are not. And more importantly, rational and thoughtful public policy would have these assessments occur before these chemicals are permitted to come onto the market. Waiting to assess the safety of chemicals after they are already in consumers’ homes and our children’s bloodstreams is totally irrational public policy.”

Commissioner Robert Adler, an attorney, seemed to be troubled that he went against the commission’s staff, and he wanted to explain his position.

“As a starting point, let me say that I have little serious disagreement with staff on the science aspect of the issues,” he said in a written statement (PDF 136 kb). “To the extent that there was disagreement, it was over the legal and policy issues arising from the science.

“I note that a large part of the staff’s recommendation rested on their misgivings about treating OFRs as a broad class of chemicals given OFRs’ differing levels of toxicity and exposure to which consumers are subject. I grant staff’s point about the differing levels of toxicity for these flame retardants. But what I have not heard from staff, nor from any of the witnesses at our hearings, is credible evidence demonstrating that there are any ‘safe’ organohalogen flame retardants.”

He said all the chemicals in the class seem to have common characteristics. For example, they pass into cells freely, do not metabolize easily, inhibit a cell’s defense system, bioaccumulate in the tissues and cause harm that can be linked to the chemical structure.

“There are certainly a number of OFRs where we have no studies to provide us with proof of harm, but years of experience confirm that every time we get sufficient data to evaluate the risk of harm of any specific OFR, we always find it to be so toxic that we start to remove it from our products. In other words, the more evidence that accumulates, the stronger we see the case against the use of these chemicals.”

As part of the coming regulatory process, the Consumer Product Safety Commission agreed to convene a chronic hazard advisory panel to assess the risks of flame retardants, drawing on all available information.

Meanwhile, the commission also issued a “guidance document” that calls on manufacturers, distributors and retailers to voluntary ensure that their products do not contain added flame retardants. Consumers, especially those who are pregnant or have young children, are advised to make sure products they purchase are free of such chemicals.

While the commission appears to be moving on a course of tough action, the regulatory process can be long and filled with potential delays. In fact, through normal appointments of commission members, President Trump will be able to change the direction of the commission over the next four years if he so chooses.

Commissioner Anne Marie Buerkle, whose term was extended by seven years in February when Trump named her to chair the commission, does not support the commission’s decision on flame retardants.

“My Democrat colleagues claim that there is ‘overwhelming scientific evidence’ of toxicity across the class; indeed, we heard witnesses at our hearing last week maintain that every organohalogen that has been adequately studied has been found to cause adverse effects,” Buerkle said in a statement (PDF 626 kb). “Even if that claim is accepted at face value, do all such adverse effects result from prevailing exposures? We know that substances as benign as oxygen and water — two of the most essential requirements for human existence — can cause death when too much is inhaled or imbibed. Is there something exceptional about organohalogens such that the dose becomes unimportant?”

Buerkle said she supports formation of a chronic hazard advisory panel, but she believes the results should be available to the commission before moving forward with regulations.

As for chemical manufacturers, it appears that they are not going down without a fight over flame retardants. A statement from the American Chemistry Council (PDF 86 kb), which represents the industry, says it will inform manufacturers and other businesses that the commission’s action has no binding effect.

“The value chain should feel confident that they can continue to use these chemistries in certain applications consistent with existing national and international regulations while CPSC conducts its further analysis of these substances,” says the statement.

Environmental and consumer groups say they will push retailers not to sell products with flame retardants, and “Consumer Reports” magazine offers recommendations about how people can avoid toxic flame retardants.

Meanwhile, Washington is among a growing number of states that have banned certain flame retardants. Based on findings from the state Department of Ecology, the Legislature approve a ban on the worst chemicals in 2008, followed by others last year. See Ecology’s webpage on the PBT Initiative.

For further reading, here are some stories from the Encyclopedia of Puget Sound:

Some toxic chemicals increase; others decline in Puget Sound fish

The importance of long-term environmental monitoring is driven home in a new study by toxicologists who have spent years examining chemical contamination in Puget Sound fish.

English sole sampling locations include both urban and rural areas of Puget Sound.
Archives of Env. Contamination and Toxicology

After 28 years of monitoring, researchers have confirmed that it is extremely difficult to remove polychlorinated biphenyls (PCBs) from the Puget Sound food web. In some locations, PCBs are actually increasing in bottom fish some 38 years after these chemicals were banned in the United States.

“Across the board, we’ve seen either no decline or even increases in our English sole, which is really kind of shocking considering all the remediation that has been going on,” said Jim West, a toxicologist with the Washington Department of Fish and Wildlife who I interviewed for a story in the Encyclopedia of Puget Sound.

The report, published in the Archives of Environmental Contamination and Toxicology, provides some bleak news about PCBs, but there are hopeful signs for other chemicals. For example, researchers were pleasantly surprised to find that toxic flame retardants containing polybrominated diphenyl ethers seem to be disappearing rapidly from the ecosystem less than a decade after the most toxic forms of PBDEs were banned in Washington state.

The study went to some lengths to make sure the decline in PBDEs in Pacific herring was not related to other factors — such as size, since the average herring is getting smaller over time.

“I now feel like this is a solid trend, and that’s really exciting,” Jim told me. “I believe it is related to our efforts in source control.”

Of course, we wouldn’t know about these long-term trends in chemical contamination were it not for long-term monitoring efforts. I discussed the importance of monitoring with Sandie O’Neill, a research scientist with WDFW. She is an author of the new study along with Jim West and Gina Ylitalo of NOAA’s Northwest Fisheries Science Center. See the related story “Monitoring helps to reveal hidden dangers in the food web” in the Encyclopedia of Puget Sound.

“We are changing people’s perspectives about contaminants throughout the (Puget Sound) watershed, including how such contaminants get into the food web,” Sandie told me.

As Sandie describes it, monitoring is needed in many aspects of ecosystem health. It can tell us whether nature is healing itself and whether restoration projects by humans are improving fish and wildlife habitat as well as human health.

EPA deal waves good-bye to toxic flame retardants

Negotiations between the Environmental Protection Agency and manufacturers of toxic flame-retardant chemicals will result in a three-year phase-out of the last polybrominated diphenyl ether, the deca form.

Steve Owens, EPA’s assistant administrator in the Office of Prevention, Pesticides and Toxic Substances, had this to say in a news release today:

“Though DecaBDE has been used as a flame retardant for years, U.S. Environmental Protection Agency has long been concerned about its impact on human health and the environment. Studies have shown that decaBDE persists in the environment, potentially causes cancer and may impact brain function. DecaBDE also can degrade to more toxic chemicals that are frequently found in the environment and are hazardous to wildlife.

“Today’s announcement by these companies to phase out decaBDE is an appropriate and responsible step to protect human health and the environment.”

Alarms bells have been sounding over PBDEs for several years. Concerns relate to liver and thyroid disease, neurological development and potential effects on the immune and reproductive systems.

Because they are persistent in the environment, these chemicals have been accumulating in the tissues of the familiar killer whales that frequent Puget Sound and the Salish Sea. See the story I wrote about toxics in orcas, October 2007.

Deca is used to reduce the risk of fire in electronics, textiles, automobiles and other applications, but other alternatives have been identified.

Today’s announcement relates to agreements with the two U.S. producers of decaBDE — Albemarle Corporation and Chemtura Corporation — along with the largest U.S. importer, ICL Industrial Products, Inc.

Under the new agreements, the companies will end production, importation and sales of decaBDE for most uses in the United States by December 31, 2012, and to end all uses by the end of 2013. Here are the letters of commitment:

Albemarle Corporation (PDF 403 kb)
Chemtura Corporation (PDF 34 kb)
ICL Industrial Products, Inc. (PDF 55 kb)

Brian Carter, global business director of Albemarle’s flame retardant group, made this comment in a prepared statement:

“While hundreds of science-based and peer-reviewed studies have shown Deca-BDE to be safe in use and one of the most efficacious flame retardants in the world, Albemarle is committed to delivering safe and effective products with increasingly smaller environmental footprints.

“Safe and environmentally sound substitutes for decabrom are available today, and we are working with our customers and the Environmental Protection Agency to implement a phase out of Deca-BDE in the coming years.”

Tony Parnell, vice president of Albemarle’s polymer solutions division, added this comment:

“In addition to our existing alternatives, Albemarle fire safety scientists have developed GreenArmor, a polymer-based flame retardant technology which is a recyclable and an eco-friendly alternative to current decabrom technology.

“Our investment in this new fire safety technology demonstrates Albemarle’s commitment to constantly seek higher-performing, sustainable alternatives to existing fire safety products.”

Meanwhile, the state of Washington remains on track to phase out PBDEs —with deca being the only one remaining. I was wondering how EPA’s agreement would mesh with Washington state’s requirements, so I called Curt Hart at the Department of Ecology.

“It is not an exact match, but it is very close,” Curt told me. “We are very pleased with the agreement that EPA has reached with these manufacturers. The good thing is that everyone now recognizes that deca is a problem as well (as other PBDEs).”

Visit Ecology’s Web site for the state’s phase-out schedule, including an important report called “Alternatives to Deca-BDE in Televisions and Computers and Residential Upholstered Furniture.”

Watching for the effects of toxic flame retardants

Whenever I write about toxic flame retardants known as polybrominated diphenyl ethers, or PBDEs, I become more convinced that we have a problem, mainly because these chemicals do not tend to break down in the environment.

Evidence indicates they are being washed into streams and tend to accumulate throughout the food web, although the trend may be slowing or even declining in Washington state, which has banned most forms of PBDEs. (Review the Water Ways entry from April 2, with links to other information sources.)

OK, so they’re a concern. But are they really harmful?

Ongoing studies have linked the chemicals to neurological and developmental problems in mice and rats, which could have implications for humans as well as other mammals.

But an important new laboratory study, by researchers with the Canadian Wildlife Service, may be the first to link the chemical to reproductive problems in birds — and at concentrations actually found in the environment.

The researchers reported that the chemicals caused thinner egg shells for American kestrels, a predatory bird that has been declining in numbers in the eastern U.S. and Canada. Furthermore, egg laying was delayed for females fed the chemicals versus those that did not get it.

The levels that caused reduced egg viability have been found not only in wild kestrels but in herring gulls and peregrine falcons as well. I would think this would be a concern for all our predatory birds, if not other species as well.

Karen Kidd and Wendy Hessler discuss these findings in the latest issue of Environmental Health News. Guess what the magazine titled their article: “Are flame retardants the next DDT?”

That refers, of course, to the chemical Dichloro-Diphenyl-Trichloroethan. Before it was banned, DDT became linked to thinning eggshells in eagle nests. DDT failed to break down readily in the environment, contaminating the entire food chain and playing a major role in the creation of the Endangered Species Act.